期刊
CHEMICAL RECORD
卷 21, 期 12, 页码 3674-3688出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/tcr.202100133
关键词
Transition-metal; Cross-coupling; C-S bond formation; Copper; C-H bond activation
资金
- Ministry of Science and Technology, Taiwan [Most 107-2113-M-005-019-MY3]
- National Chung Hsing University, i-Center for Advanced Science and Technology (iCAST)
- Innovation and Development Center of Sustainable Agriculture (IDCSA) from The Featured Areas Research Center Program
In the past decade, significant progress has been made in the construction of the C-S bond, transitioning from transitional-metal catalysis to sustainable catalysis. Various catalytic systems and sulfur precursors have been explored for C-S bond formation. A comprehensive discussion of these developed methods in terms of reactivity, sustainability, and productivity is provided in this personal account.
The recent decade evidenced a significant development in the construction of the C-S bond. The journey began with transitional-metal catalysis and reached sustainable catalysis via oxidant, photo, and electro catalyzed methods. A variety of catalytic systems have been explored for the C-S bond formation using a variety of sulfur precursors. This personal account provides an inclusive discussion of these developed methods in terms of reactivity, sustainability and productivity.
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