Synthesis and characterization of polyaniline/nickel oxide composites for fuel additive and dyes reduction

Polyaniline (PANI) and Polyaniline/Nickel oxide (PANI/NiO) composites are prepared to use as a potential catalyst, by Chemical oxidation method using ammonium persulfate (NH4)2S2O8)) as an oxidant. Nickel oxide (NiO) nanopartiles are prepared by Sol-gel method. The synthesized products were characterized by Scanning Electron Microscopy (SEM), Energy Dispersive X-ray analysis (EDX), Fourier Transform Infrared Spectroscopy (FTIR) and X-ray Diffraction technique (XRD). The prepared PANI/NiO composites are used as additive with different concentrations in diesel to investigate their efficiency as fuel additive. The catalytic properties are studied by using the synthesized products as catalyst for reduction of dyes in aqueous media. Sodium borohydride (NaBH4) is used as reducing agent. Linear relationships are obtained between time and ln(A0/At) for Methyl orange and Methylene blue. Kapp values were obtained for three catalysts showed the increasing trend of reduction for both dyes as, PANI < NiO < PANI/NiO composites. Experimental data analysis proved PANI/NiO composites to be efficient catalysts and fuel additive as compared to PANI and NiO.

Automated summary

Polyaniline (PANI) and Polyaniline/Nickel oxide (PANI/NiO) composites were prepared using ammonium persulfate as an oxidant, and characterized by various techniques; The composites were used as diesel additives, showing high efficiency; Experimental data analysis indicated that PANI/NiO composites have better catalytic and fuel additive performance compared to PANI and NiO.