Ordered macro-mesoporous nanostructure of Pd/ZrO2 catalyst for boosting catalytic NO-assisted soot oxidation

Herein, the hierarchical porous catalysts of three dimensional ordered macro-mesoporous (3DOMM) ZrO2 -supported active Pd nanoparticles (NPs) were prepared by two-step methods of evaporation-induced self-assembly-colloid crystal template (EISA-CCT) and gas bubbling-assisted membrane reduction (GBMR). Ordered macroporous structure can enhance diffusion and mass transfer of soot particles; ordered mesoporous structure is beneficial to enhance activation ability for gaseous reactants. Synergistic effect of hierarchical porous structure in the catalysts is important to improve catalytic activity for soot oxidation. Pd/3DOMM-ZrO2 catalyst exhibits the highest activity (T-50 = 404 degrees C) for soot oxidation compared with the single macroporous or mesoporous structure. The catalytic kinetics of hierarchical porous Pd/3DOMM-ZrO2 catalyst for soot oxidation was systemically investigated, i.e., its reaction rate is 0.038 mu mol g(-1) s(-1) at 310 degrees C, which is 2.7-fold of power-type Pd/normal-ZrO2 catalyst (0.014 mu mol g(-1)s(-1)). The hierarchical porous structure is a good strategy to boost catalytic activity during soot oxidation. (C) 2021 Elsevier Ltd. All rights reserved.

Automated summary

The study demonstrates the importance of hierarchical porous structure in enhancing catalytic activity for soot oxidation. The Pd/3DOMM-ZrO2 catalyst shows the highest activity compared to catalysts with single macroporous or mesoporous structure, with a higher reaction rate at lower temperatures.