期刊
CHEMICAL ENGINEERING JOURNAL
卷 420, 期 -, 页码 -出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.cej.2021.129875
关键词
Yolk-shell; Carbonization temperature; Graphitization degree; Microwave absorption
资金
- National Natural Science Foundation of China [51773060, 52073091, 51573045]
- Key Laboratory of Advanced Polymer Materials of Shanghai
The paper describes the fabrication and performance of a double-cavity yolk-shell hollow Fe3O4@C microwave absorber, which exhibits outstanding electromagnetic wave absorbing properties due to its unique structure and composition.
Carbon electromagnetic wave (EMW) absorbing materials are often limited in performance improvement due to their excessive conductivity and single loss mechanism. And the introduction of magnetic components with rational construction of microstructure is evolved as an effective approach to reinforcing the electromagnetic properties of carbon-based microwave absorbers. For the first time, a double-cavity yolk-shell hollow Fe3O4@C (H-Fe3O4@C) microwave absorber is fabricated via a coating-coating-etching method, by controlled high-temperature carbonization. The resultant carbon shell is actually composed of different contents of amorphous carbon and graphite, which has a powerful influence on the graphitization degree. When H-Fe3O4@C microspheres are carbonized at 650 degrees C, the optimized reflection loss (RL) has reached -58.44 dB and the effective bandwidth is 6.0 GHz (12.0-18.0 GHz) covering the whole Ku band with the thickness of merely 1.9 mm (filler loading: 30 wt%), which is better than most carbon-based absorbing materials reported yet. The outstanding EMW absorbing properties are ascribed to the multiple reflections and scattering arising from the designed double-cavity yolk-shell structure, the multi-interface polarization between Fe3O4/air and C/air, and the good impedance matching relating to the proper carbonization degree of carbon component at 650 degrees C.
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