4.7 Article

Synthesis and coloring properties of novel Ni-doped tialite pigments

期刊

CERAMICS INTERNATIONAL
卷 47, 期 23, 页码 33242-33251

出版社

ELSEVIER SCI LTD
DOI: 10.1016/j.ceramint.2021.08.225

关键词

Aluminum titanate; Emerald green ceramic pigments; Nickel doping; Stabilization

资金

  1. National Natural Science Foundation of China [52072162, 51962014]
  2. Jiangxi Provincial Natural Science Foundation [20202ACBL214006, 20202ACBL214008, 20192BBEL50022, 2020ZDI03004, 20202BABL21 4013, 2020GYZD013-09]
  3. Open fund project of the Key Laboratory of Inorganic Coating Materials, Chinese Academy of Science [ICM-202001]
  4. Projects of Jiangxi Provincial Department of Science and Technology [20202BABL214013]
  5. Jingdezhen science and technology plan project [20202GYZD013-09, 20202GYZD013-14]
  6. Science Foundation of Jiangxi Provincial Department of Education [GJJ201324, GJJ201345]

向作者/读者索取更多资源

Novel Ni-doped Al2TiO5 emerald green ceramic pigments were synthesized successfully for the first time, showing excellent color stability and thermal stability. The results indicate significant potential for high-temperature applications.
Novel Ni-doped Al2TiO5 emerald green ceramic pigments were successfully synthesized for the first time. Several characterization techniques (XRD, XPS, SEM, TEM, UV-Vis, and automatic colorimeters) were used to determine the phase composition and stability of the pigments, as well as the valence state of the doped nickel ion. The results show that nickel ion replaces the Al3+ in the aluminum titanate lattice in the form of Ni2+, which reduces the distortion of the octahedral structure. Ni-doping of the aluminum titanate lattice produces an excellent coloring effect and significantly promotes the synthesis and stabilization of aluminum titanate. The novel pigments have excellent color stability while maintaining exceptional coloring performance and thermal stability in a base glaze synthesized at 1200 degrees C. These pigments show considerable potential for high-temperature applications.

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