4.7 Article

Magnetic properties and magnetoresistance effect of SnFe2O4 spinel nanoparticles: Experimental, ab initio and Monte Carlo simulation

期刊

CERAMICS INTERNATIONAL
卷 47, 期 22, 页码 31886-31893

出版社

ELSEVIER SCI LTD
DOI: 10.1016/j.ceramint.2021.08.074

关键词

Tin ferrite; Nanoparticles; Magnetoresistance; Electronic structure; And Monte Carlo simulation

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In this study, SnFe2O4 nanoparticles were successfully prepared and characterized using various techniques such as X-Ray Diffraction, SEM, TEM, and SQUID. The nanoparticles showed uniform size and exhibited a large magnetoresistance effect. The experimental results were further supported by model calculations using density functional theory and Monte-Carlo simulations.
In this contribution, SnFe2O4 nanoparticles were prepared by the solvothermal method, the structural properties were performed using X-Ray Diffraction (DRX) to prove the success of tin ferrite formation and to determine de crystals parameters. The size and morphological study were build using Scanning Electron Microscopy (SEM) and Transmission Electron microscopy (TEM), the results showed that the size of particles is uniform with a range of particles (5-7 nm). The magnetic properties were carried out using the SQUID device, the SnFe2O4 nanoparticles have a magnetic transition at 750 K. In addition, the hysteresis loops at low temperature displayed Ms and Mr equals to 23 emu/g and 6 emu/g, respectively. The magnetoresistance properties were investigated, the SnFe2O4 nanoparticles present a large magnetoresistance effect (80%). The experimental results are supplemented by model calculations utilizing density functional theory and Monte-Carlo simulations.

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