La1-xCaxFeO3-δ air electrode fabricated by glycine-nitrate combustion method for solid oxide electrolysis cell

As a new type of energy conversion device, solid oxide electrolysis cell (SOEC) has attracted much attention in recent years because of its advantages such as high efficiency and unlimited capacity. At present, SOEC mainly has such issues as the element diffusion or delamination at oxygen electrode/electrolyte interface under high oxygen partial pressure, which limits its operation lifetime. In this paper, La1-xCaxFeO3-delta materials without Sr and Co were prepared by glycine-nitrate combustion method as SOEC oxygen electrodes. It is found that La0.6Ca0.4FeO3-delta (LCF64) has excellent electrical conductivity and has a coefficient of thermal expansion matching with SSZ electrolyte. The hydrogen electrode supported single cells with structure of LCF64-GDC (6:4) vertical bar GDC vertical bar SSZ vertical bar NiO-SSZ active layer vertical bar NiO-YSZ transition layer vertical bar NiO-YSZ supported layer were prepared by tape casting and co-firing method showed good electrochemical performance in SOEC mode. The electrolysis current density is 457.46 mA cm-2 with 60% H2O-H-2 atmosphere and 1.3 V applied voltage at 800 degrees C. During the constant voltage (1.3V) electrolysis process, the SOEC showed an acceptable stable current density of approximate 280 mA cm(-2) for more than 60 h.

Automated summary

This study focused on La1-xCaxFeO3-delta materials without Sr and Co as SOEC oxygen electrodes, with La0.6Ca0.4FeO3-delta (LCF64) showing excellent electrical conductivity and thermal expansion coefficient matching. The hydrogen electrode supported single cells prepared by tape casting and co-firing method exhibited good electrochemical performance in SOEC mode, with an electrolysis current density of 457.46 mA cm-2 at 800 degrees C. The SOEC showed an acceptable stable current density of approximately 280 mA cm(-2) for more than 60 hours during constant voltage electrolysis process.