期刊
CERAMICS INTERNATIONAL
卷 48, 期 1, 页码 1408-1414出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.ceramint.2021.09.227
关键词
Thermally conductive composite; Epoxyorganosiloxane; Hexagonal boron nitride; Spherical aluminum oxide
资金
- Ministry of Trade, Industry & Energy (MOTIE, Korea) [20013097]
- Min-istry of Trade, Industry & Energy (MOTIE, Korea) [20006956]
- Korea Evaluation Institute of Industrial Technology (KEIT) [20013097] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
The study focused on enhancing the thermal conductivity of h-BN composites by using an epoxyorganosiloxane with low viscosity and incorporating spherical aluminum oxides. This led to an improvement in through-plane thermal conductivity and a reduction in viscosity despite higher filler loading in the h-BN/AO hybrid composites.
Hexagonal boron nitrides (h-BNs) have received much attention as thermally conductive fillers because of their high thermal conductivity. However, their high aspect ratio hampers the realization of high filler loading by dramatically increasing viscosity and deteriorating the processability of the h-BN composites. To address this issue, an epoxyorganosiloxane with the viscosity of 250 mPa s was used to maximize h-BN loading in composites in this study. Although the BN-50 composite containing 50 wt% of h-BN achieved high in-plane thermal conductivity (5.25 W/m center dot K), its use was limited because of its low through-plane thermal conductivity (1.35 W/m center dot K) and high viscosity. To overcome this, spherical aluminum oxides (s-AOs) were incorporated into the h-BN composite with 40 wt% fillers. This increased the through-plane thermal conductivity of the h-BN/AO hybrid composites up to 2.47 W/m center dot K. Moreover, thanks to the spherical shape of AOs, the viscosity of the h-BN/AO hybrid composites was lower than that of the BN-50 composite despite higher filler loading.
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