Enhanced photocatalytic activity of ZnO/g-C3N4 nanofibers constituting carbonaceous species under simulated sunlight for organic dye removal

Semiconductor-based photocatalysis is an efficient approach for degradation of organic pollutants. In this context, ZnO/g-C3N4 composite nanofibers containing carbonaceous species with different concentrations of gC3N4 nanosheets (x = 0.25, 0.5, 1, 2, 10 wt%) noted as ZnO/carbon/(x wt%) g-C3N4 are prepared by electrospinning technique. For preparation of the composite nanofibers, bulk g-C3N4 is exfoliated to nanosheets, and then it is mixed with polyvinyl alcohol and appropriate zinc acetate content followed by electrospinning process. Thermal annealing of the as spun zinc acetate/poly(vinyl alcohol)/g-C3N4 nanosheets sample under N2 atmosphere leads to the formation of carbonaceous species (Zn-O-C) on the hexagonal wurtzite structured ZnO nanofibers. Moreover, the oxygen vacancy formed in the ZnO structure is verified by X-ray photoelectron spectroscopy (XPS) and electron spin resonance (ESR) techniques. The prepared ZnO/carbon/(0.25 wt%) g-C3N4 nanofibers demonstrated the highest photocatalytic degradation rate towards methylene blue (MB) at about 2.5 times (with degradation efficiency of 91.8% after 2 h) higher than the ZnO/carbon under similar conditions. To understand the reason behind the improved photocatalytic activity of ZnO/carbon/g-C3N4 composite nanofibers a mechanism of electron-hole generation, separation and transformation are suggested and a Z-scheme charge transfer approach is proposed.

Automated summary

Semiconductor-based photocatalysis using ZnO/g-C3N4 composite nanofibers has shown highly efficient degradation of organic pollutants, particularly with the presence of carbonaceous species. The enhanced photocatalytic activity of the composite nanofibers is attributed to the formation of carbonaceous species on the ZnO nanofibers, leading to improved degradation rates of pollutants like methylene blue. Advanced characterization techniques such as XPS and ESR have confirmed the presence of oxygen vacancies in the ZnO structure, supporting the proposed mechanism for the improved performance of the composite nanofibers.