期刊
CERAMICS INTERNATIONAL
卷 47, 期 12, 页码 17726-17735出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.ceramint.2021.03.093
关键词
Composite materials; Ceramic; Polymer; Mechanical properties; Digital light processing; Computer simulations
资金
- Spanish Ministerio de Ciencia, Innovacion y Universidades [RTI2018-095566-B-I00]
- European Regional Development Funds
Innovative scaffolds were developed using a cartesian mesh of interpenetrated composite struts of PCL and beta-TCP, with ceramic preforms fabricated through Digital Light Processing and then sintered to create co-continuous composite scaffolds infused with molten PCL. The mechanical performance of the scaffolds was notably improved after incorporating the polymeric core, with the co-continuous architecture facilitating impregnation and enhancing the isotropy of the reinforcement provided by the core, despite increasing stresses in the ceramic.
Innovative scaffolds consisting of a cartesian mesh of interpenetrated composite struts of polycaprolactone (PCL) and beta-tricalcium phosphate (beta-TCP) in a core/shell configuration are developed. Photocurable slurries with high solid-loading (40 vol% TCP) and reduced viscosity were produced by adding camphor and used to fabricate ceramic preforms with hollow struts through Digital Light Processing (DLP). After sintering the structures were suction-infiltrated by molten PCL, resulting in co-continuous composite scaffolds. Their mechanical performance was evaluated in compressive and bending tests and analyzed under the light of stress fields calculated by finite element numerical simulations. Toughness of the scaffolds was notably increased after incorporating the polymeric core. The new co-continuous architecture facilitates impregnation and improves the isotropy of the reinforcement provided by the polymeric core over other reported alternatives but increases the stresses in the ceramic. This was compensated, however, by the increased intrinsic strength associated to using a more concentrated feedstock.
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