期刊
CELLULOSE
卷 28, 期 11, 页码 7465-7481出版社
SPRINGER
DOI: 10.1007/s10570-021-04000-8
关键词
Lyocell fabric; Flame retardant; ADTPMPA; Silver nanoparticles; Antibacterial activity
资金
- National Natural Science Foundation of China [51573134]
- National Key Research and Development Program of China [2017YFB0309000]
- Beijing Tianjin Hebei collaborative innovation community construction project [20541401D]
The FR-Ag-lyocell fabric with ADTPMPA as novel flame retardant and Ag nanoparticles as coating demonstrated durable flame retardant and antibacterial properties, with LOI values reaching 44.8% and 31.3% after 20 laundering cycles, lower pHRR and THR values, and excellent antimicrobial ability against S. aureus and E. coli.
Ammonium salt of diethylene triamine penta methylene phosphonic acid (ADTPMPA), a novel flame retardant, was synthesized and grafted on the lyocell fabric to obtain a kind of flame retardant lyocell fabric (FR-lyocell). Then FR-lyocell was coated by Ag nanoparticles (Ag NPs) to fabricate flame retardant and antibacterial lyocell fabric (FR-Ag-lyocell). The elemental composition, surface morphology, combustion behavior and antibacterial activity of the lyocell fabric before and after modification were investigated. The flame retardant and antibacterial mechanism of FR-Ag-lyocell fabric was also analyzed. The limiting oxygen index (LOI) values of FR-Ag-lyocell fabric before and after 20 laundering cycles (LCs) reached 44.8% and 31.3%, respectively. The treated lyocell fabric possessed lower peak of heat release rate (pHRR) and total heat release (THR) values compared with control lyocell fabric. The FR-Ag-lyocell fabric exhibited excellent antimicrobial ability against Staphylococcus aureus (S. aureus) and Escherichia coli (E. coli), even after 10 LCs. These results indicated that FR-Ag-lyocell fabric had durable flame retardant and antibacterial properties. [GRAPHICS] .
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