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A review on chitosan-based membranes for sustainable CO2 separation applications: Mechanism, issues, and the way forward

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CARBOHYDRATE POLYMERS
卷 267, 期 -, 页码 -

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ELSEVIER SCI LTD
DOI: 10.1016/j.carbpol.2021.118178

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Chitosan; Bio-based polymer; Membrane; Flue gas; Natural gas

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Bio-based polymers, such as chitosan, offer promising advantages for gas separation membrane technology, including abundant renewable resources and reduced dependence on exhaustible fossil fuel sources. The critical study of the structure-property relationship of chitosan and its derivatives highlights potential for the design of novel bio-based membranes with improved gas permeation performance.
Effective carbon dioxide (CO2) separation by nominal energy utilization is the factual attempt in the present era of energy scarcity and environmental calamity. In this perspective, the membrane- based gas separation technology is a budding endeavour owing to its cost -effectiveness, ease of operational maintenance and compact modular design. Among various membrane materials, bio-based polymers are of interest as they are abundant and can be obtained from renewable resources, and can also reduce our dependency on exhaustible fossil fuelbased sources. In this review, the structure-property relationship of chitosan and some of its film-forming derivatives has been critically studied for the first time in view of the fundamental properties required for gas separation applications. Various factors affecting the gas permeation performance of chitosan-based membranes have been highlighted along with prospects and propositions for the design of a few novel bio-based membranes based on the exhaustive analyses.

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