Nitrogen-doped carbon composite derived from ZIF-8/ polyaniline@cellulose-derived carbon aerogel for high-performance symmetric supercapacitors

Cellulose derived carbon aerogel (CA) with unique three-dimensional network coated with polyaniline (PANI) on its surface is used as a scaffolding framework to anchor ZIF-8. The designed ZIF-8 derived porous carbon (ZC)/ PANI@CA (ZPCA) hybrid carbon composite through a facile solution immersion chemical route and subsequent carbonization process is employed as electrode for supercapacitor, which has contributed a large specific surface area, a hierarchical porous structure and reasonable N content (up to 6.27 at.%). The synthesized ZPCA electrode achieves an outstanding capacitance of 388 F g-1 at 0.5 A g-1 as well as an excellent cycling performance. More inspiringly, the symmetric supercapacitor based ZPCA achieves a high energy density of 13.4 Wh kg- 1 at a power density of 250 W kg- 1 using 2 M KOH aqueous solution, and an ultrahigh energy density of 81.8 Wh kg-1 at a power density of 950 W kg- 1 is realized using Et4NBF4/AN electrolyte.

Automated summary

The study developed a ZIF-8/PANI@CA composite material with high specific surface area and excellent capacitance performance as an electrode for supercapacitors.