4.4 Review

A review on bi/multifunctional catalytic oxydehydration of bioglycerol to acrylic acid: Catalyst type, kinetics, and reaction mechanism

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Summary: Oxydehydration of glycerol to acrylic acid is a two-step reaction involving dehydration and oxidation, requiring careful catalyst selection and reaction condition control to achieve high yield. The review focuses on recent works and critical analysis of different catalysts, highlighting the importance of specific acid sites and redox strength of active components.

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Summary: The study found that increasing the SiO2/Al2O3 molar ratio of HY zeolites decreases the total amount of acid sites per unit area, leading to a reduced initial glycerol conversion; however, the initial acrolein selectivity increases with the higher Brønsted/Lewis acid sites ratio. The catalyst lifetime depends on pore structure, with larger surface areas improving deactivation rate constants.

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Summary: The conversion of glycerol to acrylic acid is a promising application for transforming waste biomass into valuable products in the chemical industry. However, achieving high atomic efficiency and zero-waste generation remains a significant challenge. Interfacial catalysis, specifically with bimetallic nanoclusters, metal-acid composites, and acid hybrids, plays a key role in bridging nanostructured catalysts with green chemistry. Despite some initial attempts, the successful application of interfacial catalysts is still limited, but critical discussions on the catalytic properties and challenges in glycerol oxidation and dehydration to acrylic acid provide valuable insights for developing cost-effective catalytic materials for sustainable chemical applications.

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