期刊
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN
卷 94, 期 7, 页码 1999-2002出版社
CHEMICAL SOC JAPAN
DOI: 10.1246/bcsj.20210164
关键词
Excited-state planarization; Fluorescent molecule; Viscosity probe
资金
- JST FOREST Program [JPMJFR201L]
- JSPS KAKENHI [JP21H01917, JP19J22034]
The impact of nitrogen substitution on the photophysical properties and viscosity-probing function of flapping molecules has been investigated.
New synthetic protocols for nitrogen-embedded flapping molecules have been developed. Gram-scale synthesis of a key precursor, tetraamine of dibenzo[a,e]cyclooctatetraene has been established for designing flapping quinoxaline and flapping phenazineimide. The impact of the nitrogen substitution on the photophysical properties and the viscosity-probing function has been investigated in comparison with the reported flapping anthraceneimide.
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