4.8 Article

Effect of oil palm biomass cellulosic content on nanopore structure and adsorption capacity of biochar

期刊

BIORESOURCE TECHNOLOGY
卷 332, 期 -, 页码 -

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ELSEVIER SCI LTD
DOI: 10.1016/j.biortech.2021.125070

关键词

Cellulosic content; Biochar; Pyrogenic nanopores; Adsorption capacity

资金

  1. Fundamental Research Grant Scheme Malaysia Research Star Award [FRGS-MRSA/1/2018/STG07/UPM/01/1]

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This study finds that the cellulose content in biomass affects the nanopore structure and adsorption capacity of biochar, with higher cellulose content biomass producing biochar with higher adsorption capacity, which is suitable for wastewater treatment.
The influence of biomass cellulosic content on biochar nanopore structure and adsorption capacity in aqueous phase was scarcely reported. Commercial cellulose (100% cellulose), oil palm frond (39.5% cellulose), and palm kernel shell (20.5% cellulose) were pyrolyzed AT 630 ?C, characterized and tested for the adsorption of iodine and organic contaminants. The external surface area and average pore size increased with cellulosic content, where commercial cellulose formed biochar with external surface area of 95.4 m2/g and average pore size of 4.1 nm. The biochar from commercial cellulose had the largest adsorption capacities: 371.40 mg/g for iodine, 86.7 mg/L for tannic acid, 17.89 mg/g for COD and 60.35 mg/g for colour, while biochar from palm kernel shell had & nbsp;the least adsorption capacities. The cellulosic content reflected the differences in biochar nanopore structure and adsorption capacities, signifying the suitability of highly cellulosic biomass for producing biochar to effectively treat wastewater.

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