4.8 Article

Facile preparation of multi-porous biochar from lotus biomass for methyl orange removal: Kinetics, isotherms, and regeneration studies

期刊

BIORESOURCE TECHNOLOGY
卷 329, 期 -, 页码 -

出版社

ELSEVIER SCI LTD
DOI: 10.1016/j.biortech.2021.124877

关键词

Biomass; Lotus root; Freeze-drying; Direct carbonization; Dye removal

资金

  1. National Nature Science Foundation of China [21506184]
  2. Hunan Province [2019JJ50597]
  3. Key Laboratory of Powder Metallurgy
  4. Hunan 2011 Collaborative Innovation Center of Chemical Engineering with Environmental Benignity and Effective Resource Utilization

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Biomass, such as lotus root, was used to produce N-doped biochar with high surface area and partial mesopores for efficient removal of methyl orange. The biochar exhibited high capacity, fast kinetic adsorption, and good fitting to pseudo-second order and Langmuir models, showing promising potential for large-scale production and application in wastewater treatment.
Biomass is a promising carbon source because of its low-cost and rich carbon component. Here, lotus root as self N-source was used to produce N-doped biochar via a simple carbonization after freeze-drying, showing surface areas up to 694 m2/g with partial mesopores. Applicability of biochar as adsorbent for dyes removal was explored using methyl orange (MO) as model pollutant dye. LBC-800 sample obtained at 800 ?C had the largest capacity of 320 mg/g in 300 mg/L solution at 25 ?C with fast equilibrium time of 60 min, and pseudo-second order model expressed better for kinetics. LBC-800 also had an unprecedented maximum capacity of 449 mg/ g with superior conformity to Langmuir model. The biochar was efficient for MO removal with high capacity and fast kinetic, and significantly the sustainable feature of lotus root would allow a large-scale production of biochar as well as promising use in wastewater treatment fields.

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