Super Anti-Wetting Colorimetric Starch-Based Film Modified with Poly(dimethylsiloxane) and Micro-/Nano-Starch for Aquatic-Product Freshness Monitoring

Colorimetric starch film containing anthocyanins is extensively used in eco-friendly intelligent food packaging, but its high water wettability limits its practical application in the food industry. Herein, a super anti-wetting colorimetric starch film was prepared by surface modification with a nano-starch/poly-(dimethylsiloxane) (PDMS) composite coating. The water sensitivity, optical properties, mechanical properties, surface morphology, and surface chemical composition of this film were systemically investigated by multiple methods. The obtained film exhibited an extremely high water contact angle (152.46 degrees) and low sliding angle (8.15 degrees) owing to the hierarchical micro-/nanostructure formed by nano-starch aggregates combined with the low-surface-energy PDMS covering. The anti-wettability, optical barrier, and mechanical properties of this film were also significantly improved. The self-cleaning and liquid-food-repelling abilities of this film were comprehensively confirmed. Moreover, this super anti-wetting colorimetric starch film can be applied to monitor the freshness of aquatic products without being disabled by water.

Automated summary

A super anti-wetting colorimetric starch film was prepared by surface modification with a nano-starch/poly-(dimethylsiloxane) composite coating. This film exhibited extremely high water contact angle, low sliding angle, improved anti-wettability, optical barrier, and mechanical properties, along with self-cleaning, liquid-food-repelling abilities, and the ability to monitor freshness of aquatic products.