期刊
BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY
卷 17, 期 -, 页码 1518-1526出版社
BEILSTEIN-INSTITUT
DOI: 10.3762/bjoc.17.109
关键词
cyclophane; metaparacyclophane; nitration; paracyclophane; rearrangement
资金
- Massey University
[2.2]metaparacyclophanes are among the least studied simple cyclophanes, likely due to the complex syntheses. This study presents a simple synthesis method for a rare example of non-symmetric [2.2]metaparacyclophane, yielding a mixture of different products.
Substituted [2.2]metaparacyclophanes are amongst the least studied of the simple cyclophanes. This is undoubtedly the result of the lengthy syntheses of these compounds. We report the simple synthesis of a rare example of a non-symmetric [2.2]metaparacyclophane. Treatment of [2.2]paracyclophane under standard nitration conditions gives a mixture of 4-nitro[2.2]paracyclophane, 4-hydroxy-5-nitro[2.2]metaparacyclophane and a cyclohexadienone cyclophane.
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