期刊
APPLIED SPECTROSCOPY REVIEWS
卷 57, 期 2, 页码 153-176出版社
TAYLOR & FRANCIS INC
DOI: 10.1080/05704928.2021.1975126
关键词
Polyurethanes; microphase-separated structure; hard segment; soft segment
资金
- National Natural Science Foundation of China [51803107]
- Opening Fund of State Key Laboratory of Heavy Oil Processing [SKLOP202002002]
Polyurethanes (PUs) are widely used for their versatile properties of elasticity and hardness, usually with microphase-separated structures. Characterization methods such as FTIR, AFM, DSC, and SAXS are used to study these structures and their relationship with PU properties, laying a theoretical foundation for improving PU application performance.
Polyurethanes (PUs) have been versatilely applied in various fields because of their preferable properties with both elasticity and hardness. Due to the thermodynamic incompatibility of hard segments and soft segments, the PUs generally have the microphase-separated structures, which could dramatically affect their chemical and mechanical properties. In this review, the characterization methods of microphase-separated structures in PU polymers, such as fourier transformed infrared spectroscopy (FTIR), atomic force microscopy (AFM), differential scanning calorimetry (DSC), and small-angle X-ray scattering (SAXS) are summarized and illustrated. The relationship between microphase-separated structures and PU properties is also discussed. This review will lay the theoretical foundation for the improvement on the application performance of PUs.
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