期刊
APPLIED CATALYSIS B-ENVIRONMENTAL
卷 288, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.apcatb.2021.119983
关键词
Plasma functionalization; Oxygen doping; Ion energy and flux; Molecular dynamics calculation; Hydrogen evolution reaction
资金
- Hong Kong Scholars Program [XJ2018009]
- City University of Hong Kong Strategic Research Grant (SRG) [7005505]
Plasma functionalization has been shown to enhance the electrocatalytic activity of catalysts for the hydrogen evolution reaction, and this study investigates the effects of oxygen plasma processing on MoSe2 nanosheets. The findings suggest that moderate plasma parameters can improve the HER characteristics by introducing doping effects and enhancing charge transfer through the introduction of oxygen and vacancies. This research provides valuable insights into the fundamental mechanisms of plasma surface functionalization of electrochemical catalysts and highlights the importance of precise control of plasma processing parameters for efficient water splitting.
Plasma functionalization is an effective method to improve the electrocatalytic activity of catalysts for the hydrogen evolution reaction (HER), but the relationship between the plasma and catalytic activity is not clear. Herein, oxygen plasma processing is conducted on MoSe2 nanosheets and the effects of the plasma parameters including ion energy and radical flux are investigated by plasma simulation and molecular dynamics (MD) to fathom the interactions between the plasma and catalyst. A moderate ion energy and flux produce doping effects leading to proper replacement of Se sites by oxygen atoms to balance vacancy generation. Consequently, the HER characteristics are improved as exemplified by a small overpotential of 165 mV at 10 mA cm(-2) and Tafel slope of 55.2 mV dec(-1). Based on first-principles density-functional theory calculation, increased polarization and state density distributions close to the Femi level introduced by oxygen and vacancies reduce the bandgap and Delta G(H) at the Mo, Se, and O sites, consequently enhancing charge transfer between the catalyst and electrolyte. The results convey new fundamental knowledge about plasma surface functionalization of electrochemical catalysts and enable precise and optimal selection of plasma processing parameters to control and balance the active sites for efficient water splitting.
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