4.8 Article

Co-conversion of lignocellulosic derivatives to jet fuel blending by an efficient hydrophobic acid resin

期刊

APPLIED CATALYSIS B-ENVIRONMENTAL
卷 292, 期 -, 页码 -

出版社

ELSEVIER
DOI: 10.1016/j.apcatb.2021.120181

关键词

Bio-jet fuel; Biomass conversion; C-C coupling reaction; Co-conversion; Solid acid catalyst

资金

  1. National Natural Science Foundation of China [21808162, 21978200]
  2. National Postdoctoral Program for Innovative Talents [BX20180212]
  3. China Postdoctoral Science Foundation [2018M631743]

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The study demonstrates the efficient synthesis of high-performance jet fuel through co-conversion of lignocellulosic derivatives catalyzed by R-x resin. R-x shows better activity and recycling stability, leading to a product yield of 75.4% in the conversion process.
Bio-jet fuel synthesis is a promising way to upgrade the value of lignocellulose and contributes to the sustainable development. Presently the property of bio-jet fuel is weakened by single component produced using pure feedstock and water produced in the reaction leading to acid leaching. Therefore, we synthesized a hydrophobic acid resin (R-x) and used it to catalyze lignocellulose-derived mixture upgrading to high-performance bio-jet fuel blending, where R-x shows better activity than Amberlyst-15, Nafion-212 and H beta with 75.4% of product yield obtained in co-conversion of lignocellulosic derivatives. The better activity of R-x is ascribed to the strong acid, big acid concentration, large surface area and especially super hydrophobicity resulting as R-x recycled steadily in consecutive 5 runs. After hydrodeoxygenation, jet fuel blending with high density and excellent freezing point better than JP-7 was obtained. This work demonstrates an efficient catalyzing method to synthesize highperformance jet fuel by co-conversion of lignocellulosic derivatives.

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