Mixture of α-Fe2O3 and MnO2 powders for direct conversion of syngas to light olefins

Although the direct conversion of syngas to light olefins (C-2(=)-C-4(=)) via Fischer-Tropsch synthesis (FTS) has made great progress, it remains a substantial challenge to elucidate the roles of iron carbides and promoters, due to the observed results are caused by numerous complexities and uncertainties. Herein, in order to better avoid the influence of diffusion rate, metal-inert support interaction, and reduce the effects of promoter on the coverage of active sites, a mixture of alpha-Fe2O3 and MnO2 powders catalyst was developed to understand the role of iron carbides in the formation of light olefins during the FTS. The characterization results confirmed that the interaction of Fe-Mn was formed on the surface of iron powder, and the electronic state of iron atoms was affected due to the existence of promoter MnO2 during carburization. Significantly, the results from in situ XPS and Mossbauer spectroscopy further evidence that promotion of the electron transfer from MnO2 to Fe2O3 facilitated the formation of C-poor theta-Fe3C, contributing to enrich the reactivity for the syngas to light olefins.

Automated summary

The interaction of Fe-Mn and promotion of electron transfer from MnO2 to Fe2O3 facilitate the formation of C-poor theta-Fe3C, enriching the reactivity for syngas to light olefins. Characterization techniques confirmed the impact of these interactions, providing valuable insights into the role of iron carbides in Fischer-Tropsch synthesis.