期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 60, 期 45, 页码 24131-24136出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.202107613
关键词
alkali metals; alkaline earth metals; diomand-like structures; nonlinear optics; quaternary chalcogenides
资金
- High-level Talent Project of Xinjiang Uygur Autonomous Region [2020000039]
- Tianshan Cedar Program [2019XS24]
- National Natural Science Foundation of China [52002398]
- Xinjiang Key Laboratory of Electronic Information Materials and Devices [2017D04029]
Li4MgGe2S7 is an infrared NLO material with a large band gap and strong nonlinear optical effect, promising a high laser damage threshold and suitable SHG response. It provides insights into the design of new DL compounds with outstanding IR NLO performances.
Large band gap and strong nonlinear optical (NLO) effect are two valuable but contradictory parameters, which are difficult to balance in one infrared (IR) NLO material. Herein, the first alkali and alkaline-earth metal diamond-like (DL) IR NLO material Li4MgGe2S7, presenting a honeycomb-like 3D framework constructed by 6-membered LiS4 rings and GeMgS6 zigzag chains, was rationally designed and synthesized. The introduction of rigid alkali metal and alkaline-earth metal LiS4 and MgS4 tetrahedra effectively broadens the band gap of DL compound to 4.12 eV (the largest one in the reported quaternary metal chalcogenides), generating a high laser damage threshold of 7 x AgGaS2 at 1064 nm. Furthermore, Li4MgGe2S7 displays a suitable SHG response (0.7 x AgGaS2) with a type I phase-matching behavior. The results indicate that Li4MgGe2S7 is a promising IR NLO material for the high-power laser application and it provides an insight into the design of new DL compound with outstanding IR NLO performances.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据