期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 60, 期 46, 页码 24500-24504出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.202111396
关键词
alkenes; arylation; chain walking; palladium; beta-acetoxy elimination
资金
- JSPS KAKENHI [JP18H01985, JP15KT0069]
- Asahi Glass Foundation
- Keio University from Ushioda Memorial Fund
Palladium-catalyzed remote arylative substitution was achieved for the reaction of arylboronic acids with alkenes possessing a distant acetoxy group, providing arylation products with an alkene moiety at the remote position with good regioselectivity. This reaction is applicable to various arylboronic acids and alkene substrates.
Palladium-catalyzed remote arylative substitution was achieved for the reaction of arylboronic acids with alkenes possessing a distant acetoxy group to provide arylation products having an alkene moiety at the remote position. The use of beta-acetoxy elimination as a key step in the catalytic cycle allowed for regioselective formation of unstabilized alkenes after chain walking. This reaction was applicable to various arylboronic acids as well as alkene substrates.
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