期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 60, 期 35, 页码 19374-19382出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.202106640
关键词
(meth)acrylates; biobased polymers; one-pot catalysis; reaction mechanisms; renewable monomers
资金
- Chimie ParisTech - PSL
- CNRS
- Pcole polytechnique (AMX)
- CSC
- 500 MHz NMR spectrometer of Chimie ParisTech in the framework of the SESAME equipment project
- Bio-Based Industries Joint Undertaking under the European Union's Horizon 2020 research and innovation program [744349]
The study introduces a one-pot catalytic system that can efficiently transform renewable materials into monomers suitable for polymer production, enabling the synthesis of a new library of unique poly(meth)acrylates under mild conditions.
Shifting from petrochemical feedstocks to renewable resources can address some of the environmental issues associated with petrochemical extraction and make plastics production sustainable. Therefore, there is a growing interest in selective methods for transforming abundant renewable feedstocks into monomers suitable for polymer production. Reported herein are one-pot catalytic systems, that are active, productive, and selective under mild conditions for the synthesis of copolymers from renewable materials. Each system allows for anhydride formation, alcohol acylation and/or acid esterification, as well as polymerization of the formed (meth)acrylates, providing direct access to a new library of unique poly(meth)acrylates.
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