期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 60, 期 42, 页码 22706-22710出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.202108498
关键词
carbenes; dithiolenes; silicon; silylenes; sulphur
资金
- National Science Foundation [CHE-1855641, CHE-2134792]
The study investigated reactions between Lewis bases and an imidazole-based dithione dimer, revealing that both cyclic(alkyl)(amino)carbene and N-heterocyclic carbene can cleave the sulfur-sulfur bonds in the dimer, producing carbene-stabilized dithiolene zwitterions and a spirocyclic silicon-dithiolene compound. The bonding nature of the products was examined using experimental and theoretical methods.
A series of reactions between Lewis bases and an imidazole-based dithione dimer (1) has been investigated. Both cyclic(alkyl)(amino)carbene (CAAC) (2) and N-heterocyclic carbene (NHC) (4), in addition to N-heterocyclic silylene (NHSi) (6), demonstrate the capability to cleave the sulphur-sulphur bonds in 1, giving carbene-stabilized dithiolene (L-0) zwitterions (3 and 5) and a spirocyclic silicon-dithiolene compound (7), respectively. The bonding nature of 3, 5, and 7 are probed by both experimental and theoretical methods.
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