期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 60, 期 38, 页码 21025-21032出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.202108624
关键词
nonflammable electrolytes; organic cathodes; Zn-anodes; Zn-organic batteries
资金
- National Key Research and Development Program of China [2018YFE0201702]
- National Natural Science Foundation of China [21975052, 21935003, 21805126]
A new organic electrolyte containing zinc trifluoromethanesulfonate salt and a mixed solvent has been proposed for zinc batteries, which shows high ionic conductivity, wide potential window, and dendrite-free zinc plating/stripping. A 2 V zinc//polytriphenylamine composite battery fabricated with the optimized electrolyte exhibits high performance and long cycle life even with high mass-loading of PTPAn in the cathode and high zinc-utilization.
Owing to undesired Zn corrosion and the formation of Zn dendrites in aqueous electrolytes, most of the examples of aqueous Zn batteries with reported excellent performance are achieved with low Zn-utilization (<0.6 %) in the anode and low mass-loading (<3 mg cm(-2)) in the cathode. Herein, we propose a new organic electrolyte for Zn batteries, which contains a zinc trifluoromethanesulfonate (Zn-TFMS) salt and a mixed solvent consisting of propylene carbonate (PC) and triethyl phosphate (TEP). We demonstrate that this electrolyte with an optimized PC/TEP ratio not only exhibits high ionic conductivity and a wide stable potential window, but also facilitates dendrite-free Zn plating/stripping. In particular, the TEP solvent makes the electrolyte nonflammable. Finally, a 2 V Zn//polytriphenylamine composite (PTPAn) battery is fabricated with the optimized electrolyte; it shows a high rate and a long lifetime (2400 cycles) even with a high mass-loading (16 mg cm(-2)) of PTPAn in the cathode and with a high Zn-utilization (3.5 %).
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