期刊
ADVANCED MATERIALS
卷 33, 期 27, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.202008784
关键词
energy storage materials; metal‐ organic frameworks; metal– sulfur batteries; nanostructures; porous carbon; polysulfide catalysts; polysulfide electrodes
类别
资金
- National Key R&D Program of China [2019YFA0110600, 2019YFA0110601]
- National Natural Science Foundation of China [82071938, 82001824, 82001829, 51903178, 81971622, 51803134, 51703141]
- Science and Technology Project of Sichuan Province [2020YFH0087, 18YYJC1417, 2019YFS0219, 2020YJ0055]
- Deutsche Forschungsgemeinschaft (DFG, German Research Foundation) under Basismodul, Eigene Stelle [LI 3545/1-1]
- State Key Laboratory of Polymer Materials Engineering [sklpme2019-2-03]
- Fundamental Research Funds for the Central Universities, Thousand Youth Talents Plan
- Alexander von Humboldt Fellowship
- Projekt DEAL
Metal-sulfur batteries are considered promising future energy storage systems due to their high theoretical energy density, but their practical applications are hindered by challenges such as shuttle effects and low conductivity of sulfur species. Recently, metal-organic frameworks-derived nanostructures have emerged as efficient multifaceted electrodes in MSBs, showing high surface area and molecular/atomic-level reactive sites. This review discusses the advancements in designing MOF-derived electrodes and their impact on electrochemical properties, providing guidance for the future development of fast-kinetic and robust MSBs in broad energy fields.
Metal-sulfur batteries (MSBs) are considered up-and-coming future-generation energy storage systems because of their prominent theoretical energy density. However, the practical applications of MSBs are still hampered by several critical challenges, i.e., the shuttle effects, sluggish redox kinetics, and low conductivity of sulfur species. Recently, benefiting from the high surface area, regulated networks, molecular/atomic-level reactive sites, the metal-organic frameworks (MOFs)-derived nanostructures have emerged as efficient and durable multifaceted electrodes in MSBs. Herein, a timely review is presented on recent advancements in designing MOF-derived electrodes, including fabricating strategies, composition management, topography control, and electrochemical performance assessment. Particularly, the inherent charge transfer, intrinsic polysulfide immobilization, and catalytic conversion on designing and engineering of MOF nanostructures for efficient MSBs are systematically discussed. In the end, the essence of how MOFs' nanostructures influence their electrochemical properties in MSBs and conclude the future tendencies regarding the construction of MOF-derived electrodes in MSBs is exposed. It is believed that this progress review will provide significant experimental/theoretical guidance in designing and understanding the MOF-derived nanostructures as multifaceted electrodes, thus offering promising orientations for the future development of fast-kinetic and robust MSBs in broad energy fields.
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