期刊
ADVANCED MATERIALS
卷 33, 期 41, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.202102212
关键词
atomic-level Ni-Zn pair sites; enhanced CO; (2) electroreduction; mechanistic understanding; synergistic effects; thermodynamic pathways; kinetic pathways
类别
资金
- Zhejiang University
- National Key R&D Program of China [2018YFA0209600]
- Natural Science Foundation of China [22022813, 21878268]
- DNL Cooperation Fund, CAS [DNL201903]
- National Natural Science Foundation of China [51701201]
- National Key Research and Development Program of China [2017YFB0702100]
Dual-atom catalysts have shown potential to outperform single-atom catalysts in the electrochemical conversion of CO2 due to a synergistic effect observed in atomically dispersed Ni-Zn bimetal sites. The heteronuclear coordination modifies the d-states of the metal atom, narrowing the gap between εd and EF to strengthen electronic interaction at the reaction interface, leading to improved catalytic efficiency.
Dual-atom catalysts have the potential to outperform the well-established single-atom catalysts for the electrochemical conversion of CO2. However, the lack of understanding regarding the mechanism of this enhanced catalytic process prevents the rational design of high-performance catalysts. Herein, an obvious synergistic effect in atomically dispersed Ni-Zn bimetal sites is observed. In situ characterization combined with density functional theory (DFT) calculations reveals that heteronuclear coordination modifies the d-states of the metal atom, narrowing the gap between the d-band centre (epsilon(d)) of the Ni (3d) orbitals and the Fermi energy level (E-F) to strengthen the electronic interaction at the reaction interface, resulting in a lower free energy barrier (Delta G) in the thermodynamic pathway and a reduced activation energy (E-a) as well as fortified metal-C bonding in the kinetic pathway. Consequently, a CO faradaic efficiency of >90% is obtained across a broad potential window from -0.5 to -1.0 V (vs RHE), reaching a maximum of 99% at -0.8 V, superior to that of the Ni/Zn single-metal sites.
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