期刊
ADVANCED FUNCTIONAL MATERIALS
卷 31, 期 37, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adfm.202104369
关键词
asymmetric; isomer; non-fullerene acceptor; organic solar cells
类别
资金
- APRC Grant of the City University of Hong Kong [9380086, 9610421]
- Innovation and Technology Fund [ITS/497/18FP, GHP/021/18SZ]
- Office of Naval Research [N00014-20-1-2191]
- ECS grant from the Research Grants Council of Hong Kong [CityU 21301319]
- Natural Science Foundation of Guangdong Province [2019A1515010761, 2019A1515011131]
- Guangdong Major Project of Basic and Applied Basic Research [2019B030302007]
- Guangdong-Hong Kong-Macao joint laboratory of optoelectronic and magnetic functional materials [2019B121205002]
- Shenzhen Science and Technology Innovation Committee [JCYJ20180507181718203]
- National Natural Science Foundation of China [21905103]
- Lee Shau-Kee Chair Professor (Materials Science)
By systematically exploring asymmetric isomer effects, new non-acyclic electron acceptors were designed and synthesized to significantly improve the power conversion efficiency of organic solar cells. The asymmetric isomerization strategy effectively inhibits molecular aggregation and unfavorable orientations, leading to more efficient dissociation and optimized microstructure, resulting in a remarkably higher PCE.
Herein, asymmetric isomer effects are systematically explored by designing and synthesizing two benzo[c][1,2,5]thiadiazole (BT)-fused nonacyclic electron acceptors. By changing from BP6T-4F to asymmetric ABP6T-4F, significantly enhanced dielectric constant and inhibited excessive molecular aggregation and unfavorable edge-on orientation could be achieved. The reduced exciton binding energy also facilitates a more efficient dissociation process in PM6:ABP6T-4F compared to PM6:BP6T-4F with the same energy offset. Moreover, the weaker crystallization behavior enables a significantly enhanced miscibility between PM6 and ABP6T-4F than that between PM6 and BP6T-4F, which leads to an optimized micromorphology with smooth surface, suitable domain size, and ordered pi-pi stacking. Organic solar cells (OSCs) based on PM6:ABP6T-4F achieve a 15.8% power conversion efficiency (PCE), which is remarkably higher than that of PM6:BP6T-4F-based OSCs (6.4%). Furthermore, ternary devices are also fabricated considering good compatibility between ABP6T-4F and CH1007 to deliver a PCE over 17%. This study reveals the effectiveness and great potential of asymmetric isomerization strategy in regulating molecular properties, which will provide guidance for the future design of non-fullerene acceptors.
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