4.8 Article

Fly Ash Carbon Anodes for Alkali Metal-Ion Batteries

期刊

ACS APPLIED MATERIALS & INTERFACES
卷 13, 期 22, 页码 26421-26430

出版社

AMER CHEMICAL SOC
DOI: 10.1021/acsami.1c06543

关键词

fly ash carbon; alkali metal-ion batteries; carbon anode; surface chemistry; oxygen functional groups

资金

  1. King Abdullah University of Science and Technology.King Abdulaziz University (KAUST-KAU) Initiative [OSR-2018 KAUST-KAU-3903]

向作者/读者索取更多资源

Graphite plays a crucial role in the battery industry, but its synthesis process is energy-intensive. Graphite anodes in sodium-ion and potassium-ion batteries exhibit poor capacities and cycling stability, hindering the development of next-generation battery technologies. Using fly ash carbon as an anode material shows promising performance and scalability for alkali metal-ion batteries.
Graphite has become a critical material because of its essential role in the lithium-ion battery (LIB) industry. However, the synthesis of graphite requires an energy-intensive thermal treatment. Also, when used in sodium-ion and potassium-ion batteries (SIBs and PIBs), the graphite anode shows poor capacities and cycling stability, which hinders the development of next-generation battery technologies. Finding suitable anode materials for commercial alkali metal-ion batteries is not only urgent for the energy storage industry, but is also important for economic and sustainable development. In this work, we use fly ash carbon (FAC), a residue of crude oil combustion, as an anode material for alkali metal-ion batteries. The FAC anodes show relatively high capacities and excellent cycling stability. The charge storage mechanism of FAC anode is shown to be intercalation coupled with redox reactions of oxygen functional groups. This work shows that FAC is a promising scalable anode material for alkali metal-ion batteries.

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