Bipolar Aggregation-Induced Electrochemiluminescence of Thiophene-Fused Conjugated Microporous Polymers

Herein, we synthesize the thiophene tetraphenylethene-based conjugated microporous polymer (ThT-CMP) using the tetraphenylethylene derivative [i.e., 1,1,2,2-tetrakis(4-bromophenyl)-ethane (TPBE)] and 2,5-thiophenediboronic acid as the precursors. The aggregation of TPBE in the ThT-CMP can induce a strong dual-band bipolar electrochemiluminescence (AIECL) emission at 554 nm (anodic) and 559 nm (cathodic) with tri-n-propylamine (TPrA) and S2O82- as the coreactants, respectively. The anodic and cathodic ECL efficiencies are measured to be 11.49 and 3.82% with respect to the standard of the Ru(bpy)(3)(2+)/TPrA system, respectively. We further develop a dipolar ECL sensor to sensitively detect rhodamine B (RhB) based on resonance energy transfer. This ECL sensor possesses a large dynamic range and high sensitivity. This research provides a new avenue of designing organic structures with the characteristic of bipolar AIECL for the development of luminescent devices.

Automated summary

The study successfully induced strong dual-band bipolar electrochemiluminescence with ThT-CMP and TPBE, emitting at 554 nm (anodic) and 559 nm (cathodic). A dipolar ECL sensor based on resonance energy transfer was further developed to sensitively detect RhB, displaying a large dynamic range and high sensitivity. This research opens up possibilities for designing organic structures with bipolar AIECL characteristics for luminescent device development.