期刊
ACS APPLIED MATERIALS & INTERFACES
卷 13, 期 27, 页码 32467-32478出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsami.1c06452
关键词
cellulose fibers; filter paper; CNF; nanofibrillation; green materials
资金
- strategic innovation program BioInnovation
- Vinnova
- Formas
- Swedish Energy Agency
- BillerudKorsnas AB
- Knut and Alice Wallenberg foundation through the Wallenberg Wood Science Centre
This study provides an in-depth characterization of self-fibrillating cellulose fibers and demonstrates their use in smart, responsive filters capable of regulating flow and retaining nanoscale particles. Through visualization of the swelling process using various microscopy techniques, smart filters prepared via in situ nanofibrillation show efficient filtration and retention abilities.
Thorough characterization and fundamental understanding of cellulose fibers can help us develop new, sustainable material streams and advanced functional materials. As an emerging nanomaterial, cellulose nanofibrils (CNFs) have high specific surface area and good mechanical properties; however, handling and processing challenges have limited their widespread use. This work reports an in-depth characterization of self-fibrillating cellulose fibers (SFFs) and their use in smart, responsive filters capable of regulating flow and retaining nanoscale particles. By combining direct and indirect characterization methods with polyelectrolyte swelling theories, it was shown that introduction of charges and decreased supramolecular order in the fiber wall were responsible for the exceptional swelling and nanofibrillation of SFFs. Different microscopy techniques were used to visualize the swelling of SFFs before, during, and after nanofibrillation. Through filtration and pH adjustment, smart filters prepared via in situ nanofibrillation showed an ability to regulate the flow rate through the filter and a capacity of retaining 95% of 300 nm (diameter) silica nanoparticles. This exceptionally rapid and efficient approach for making smart filters directly addresses the challenges associated with dewatering of CNFs and bridges the gap between science and technology, making the widespread use of CNFs in high-performance materials a not-so-distant reality.
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