4.8 Article

Challenges for Incorporating Optical Switchability in Organic-Based Electronic Devices

期刊

ACS APPLIED MATERIALS & INTERFACES
卷 13, 期 24, 页码 27737-27748

出版社

AMER CHEMICAL SOC
DOI: 10.1021/acsami.1c05489

关键词

molecular switches; azobenzene; diarylethene; self-assembled monolayers; molecular junctions

资金

  1. European Commission via the Seventh Framework Program (FP7/2007-2013) project ITN SUPERIOR [238177]
  2. Marie Curie project ITN iSwitch [642196]
  3. Belgian National Fund for Scientific Research (F.R.S.-FNRS)
  4. F.R.S.-FNRS [2.5020.11]
  5. Walloon Region [1117545]

向作者/读者索取更多资源

This research introduces different concepts implemented in organic thin films and molecular junctions, as well as a new method of incorporating photochromic molecules into organic electronic devices. The discussion also highlights some issues that have been emphasized through theoretical modeling.
Transistors operate by controlling the current flowing from a source to a drain electrode via a third electrode (gate), thus giving access to a binary treatment (ON/OFF or 0/1) of the signal currently exploited in microelectronics. Introducing a second independent lever to modulate the current would allow for more complex logic functions amenable to a single electronic component and hence to new opportunities for advanced electrical signal processing. One avenue is to add this second dimension with light by incorporating photochromic molecules in current organic-based electronic devices. In this Spotlight, we describe different concepts that have been implemented in organic thin films and in molecular junctions as well as some pitfalls that have been highlighted thanks to theoretical modeling.

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