期刊
ACS APPLIED MATERIALS & INTERFACES
卷 13, 期 30, 页码 35785-35794出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsami.1c09120
关键词
oxide glass electrolyte; cold press; all-solid-state battery; full battery cell; Li2S-Si battery
The study explores Li2SO4-Li2CO3-LiX oxide glass systems as highly deformable and high-ionic-conductive oxide electrolytes suitable for all-solid-state lithium-ion batteries. LiI oxide glass works well for the negative electrode due to its high ionic conductivity, while LiCl or LiBr oxide glasses are suitable for the positive electrode and separation layer. The use of these oxide glass systems in composite electrodes improves battery performance, indicating potential for high-capacity and safe all-solid-state batteries.
Oxide-type all-solid-state lithium-ion batteries have attracted great attention as a candidate for a next-generation battery with high safety performance. However, batteries based on oxide systems exhibit much lower energy densities and rate performances than liquid-type lithium-ion batteries, owing to the difficulty in preparing the ion- and electron-transfer path between particles. In this study, Li2SO4-Li2CO3-LiX (X = Cl, Br, and I) glass systems are investigated as highly deformable and high-ionic-conductive oxide electrolytes. These electrolytes show excellent deformable properties and better ionic conductivity. The LiI oxide glass system is a suitable electrolyte for the negative electrode because it shows a higher ionic conductivity and is stable up to 2.8 V. The LiCl or LiBr oxide glass systems are suitable electrolytes for the positive electrode and separation layer because they show high ionic conductivity and kinetic stability up to 3.2 V. The Li2S positive and Si negative composite electrodes employing LiBr and LiI oxide glass electrolytes, respectively, show high battery performances because of increased reaction points between active materials and the solid electrolyte and carbon via a mechanical milling process and are capable of forming good interparticle contact. Therefore, it suggests that the excellent deformable electrolytes are suitable for solid electrolytes in composite electrodes because their ionic conductivity does not change by the mechanical milling process. Furthermore, an oxide-type all-solid-state Li2S-Si full-battery cell employing these positive and negative composite electrodes and a LiBr oxide glass electrolyte separation layer is demonstrated. The full-battery cell indicates a relatively high discharge capacity of 740 mA h g(-1)(Li2S) and an area capacity of 2.8 mA h cm(-2) at 0.064 mA cm(-2) and 45 degrees C despite using only safe oxide electrolytes.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据