4.7 Article

Enhanced the thermal conductivity of hydroxyl-terminated polybutadiene (HTPB) composites by graphene-silver hybrid

期刊

COMPOSITES COMMUNICATIONS
卷 24, 期 -, 页码 -

出版社

ELSEVIER SCI LTD
DOI: 10.1016/j.coco.2021.100661

关键词

GNs-Ag hybrids; Hydroxyl-terminated polybutadiene (HTPB); Heat conductivity; Mechanical properties

资金

  1. Anhui Provincial Natural Science Foundation [2008085ME138]
  2. Scientific Research Fund of Anhui Provincial Education Department [KJ2018A0038, KJ2020A0015]
  3. Anhui Province Institute of High Performance Rubber Materials and Products
  4. 211 Project of Anhui University

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The addition of Graphene-Silver (GNs-Ag) hybrids as fillers significantly increased the thermal conductivity of HTPB, improving the mechanical properties and thermal stability of the composites.
The heat conductivity affects the burning rate of propellant much, which would influence the properties of power propellant. In this work, hydroxyl-terminated polybutadiene (HTPB) was employed as a model propellant matrix, and series of composites were fabricated by introducing Graphene-Silver (GNs-Ag) hybrid as fillers to improve the heat conductivity of HTPB. GNs-Ag hybrids were prepared via chemical reduction of silver onto the graphene nanosheets, and the effect of preparation conditions on the fabrication of GNs-Ag were studied systematically. With the addition 0.5 wt% of GNs-Ag hybrid, the GNs-Ag/HTPB composites had a 52.6% increase in thermal conductivity compared with that of neat HTPB. The mechanical properties and thermal stability of the GNs-Ag/ HTPB nanocomposites were also sightly improved.

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