期刊
ENERGY STORAGE MATERIALS
卷 36, 期 -, 页码 272-278出版社
ELSEVIER
DOI: 10.1016/j.ensm.2021.01.001
关键词
Electroless plating; high softness; metal-conductive cloth; flexible Ag//Zn battery; flexible Ni//Zn battery
资金
- National Key R&D Program of China [2019YFA0705104]
The research focuses on the development of flexible wearable batteries using metal-conductive cloths, achieving high conductivity and coverage of active materials while maintaining softness, demonstrating excellent performance and high flexibility.
High flexibility, as one target for wearable batteries, requires each component of battery devices to be soft. However, softness, as an index reflecting the soft degree, was seldom applied in battery field. Here, several metal-deposited soft substrates, including cloth, paper and sponge were produced using a universal electroless plating method. High conductivity (4 similar to 200 kS m(-1)) and high coverage of active materials was achieved without sacrificing the softness (similar to 8 mm) of cotton cloth. Given such a visible value, the softness of the total battery device can be tuned. Consequently, batteries based on these metal-conductive cloths show excellent performance and high softness. The assembled Ag cloth//Zn battery delivered a stable output of 1.0 mAh cm(-2) with a softness of 4.21 mm. The Ni cloth//Zn battery provided a high discharge capacity of 0.98 mAh cm(-2) at 4 mA cm(-2) with a high discharge plateau around 1.7 V (energy density of 1.7 mWh cm(-2) at a power density of 8.5 mW cm(-2)). Moreover, a large size (360 cm(2)) of flexible Ni cloth//Zn device with a softness of 3.34 mm and discharge capacity of 132 mAh is fabricated and mounted on a human cloth to power electronics.
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