期刊
EUROPEAN POLYMER JOURNAL
卷 85, 期 -, 页码 279-297出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.eurpolymj.2016.10.031
关键词
Devulcanized rubber; Copolyester; Thermoplastic vulcanizates; Devulcanization; Thermo-chemical method
资金
- Higher Education Research Promotion
- National Research University Project of Thailand, Office of the Higher Education Commission [SIT580663S]
Devulcanized rubber (DR) was prepared from used truck tires via thermo-chemical devulcanization. Effects of devulcanizing reaction time and temperature were studied, and the DR contained higher sol fraction but had lower crosslink density than un-devulcanized rubber (UDR). Furthermore, the soluble fraction (sol fraction) increased with devulcanizing time and temperature. Devulcanizing for 4 min at 180 degrees C was chosen as the most efficient alternative. Then, thermoplastic vulcanizates (TPVs) from blends of copolyester (COPE) with two alternative types of recycled rubber (i.e., DR and UDR) were prepared and their mechanical, morphological, rheological, thermal and swelling properties were investigated. It was found that the dynamically cured DR/COPE blends exhibited higher mechanical and thermal resistance than the dynamically cured UDR/COPE blends. Furthermore, the complex viscosity and storage modulus of the dynamically cured DR/COPE blends decreased with devulcanizing time, due to breakdown of the rubber network and the carbon main chains in rubber molecules. In addition, phase separated micron-sized vulcanized rubber domains were finely dispersed in the COPE matrix, and their size correlated well with the mechanical strength and other related properties. However, the rubber domains agglomerated with excessive devulcanization, causing inferior mechanical strength. (C) 2016 Elsevier Ltd. All rights reserved.
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