期刊
EUROPEAN POLYMER JOURNAL
卷 74, 期 -, 页码 26-37出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.eurpolymj.2015.11.008
关键词
Renewable resources; Fatty acid; Glycidol; Organic carbonate; Polyhydroxyurethanes (PHUs); Photopolymerization
资金
- Centre National de la Recherche Scientifique (CNRS)
- University of Bourgogne Franche-Comte
- Department of Electrochemistry, Molecular Materials, and Devices (EMMD-ICMUB)
- Conseil Regional de Bourgogne (France)
An undecylenic acid-based monoglyceride prepared from glycidol and undecylenic acid is used as suitable and tunable synthon for polymerization applications. Epoxidation and acrylation reactions lead to photopolymerizable monomers while transesterification with dimethyl carbonate, metathesis and aminolysis reactions provide access to polyhydroxyurethane-based Materials. The successive intermediates were synthesized according to a green chemistry approach implicating solvent-less and catalyzed reactions, and were at each step fully characterized by infrared, H-1 and C-13{H-1} NMR spectroscopy, elemental analysis and mass spectrometry. Analyses of the resulting polymer materials were performed by infrared, H-1 and C-13{H-1} NMR, thermogravimetric analysis (TGA), differential scanning calorimetry (DSC) and gel permeation chromatography (GPC). (C) 2015 Elsevier Ltd. All rights reserved.
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