期刊
ADVANCED SCIENCE
卷 8, 期 12, 页码 -出版社
WILEY
DOI: 10.1002/advs.202100072
关键词
all‐ polymer approach; crease‐ free; self‐ healing capabilities; supercapacitors; supramolecular hydrogels
资金
- National Key R&D Program of China [2019YFA0705104]
- GRF Scheme [CityU 11305218]
- Science Technology and Innovation Committee of ShenzhenMunicipality [JCYJ20170818103435068]
- Project of International Science and Technology Cooperation in Guangdong Province [2020A0505100016]
An all-polymeric, all-elastic and non-laminated supercapacitor has been developed to address structural problems and increase mechanical reliability, while maintaining excellent electrochemical performance. This innovative design includes in situ integration of a polypyrrole electrode layer into a silk fibroin-based elastic supramolecular hydrogel film, resulting in a device with structural elasticity at the device level. Additionally, the supercapacitors exhibit outstanding self-healing capabilities, with a self-healing efficiency approaching 95.8% even after 30 cutting/healing cycles.
While traditional three-layer structure supercapacitors are under mechanical manipulations, the high-stress region concentrates, inevitably causing persistent structural problems including interlayer slippage, crease formation, and delamination of the electrode-electrolyte interface. Toward this, an all-polymeric, all-elastic and non-laminated supercapacitor with high mechanical reliability and excellent electrochemical performance is developed. Specifically, a polypyrrole electrode layer is in situ integrated into a silk fibroin-based elastic supramolecular hydrogel film with extensive hydrogen and covalent bonds, where a non-laminate device is realized with structural elasticity at the device level. The non-laminate configuration can avoid slippage and delamination, while the elasticity can preclude crease formation. Furthermore, under more severe mechanical damage, the supercapacitors can restore the electrochemical performance through non-autonomous self-healing capabilities, where the supramolecular design of host-guest interactions in the hydrogel matrix results in a superior self-healing efficiency approaching approximate to 95.8% even after 30 cutting/healing cycles. The all-elastic supercapacitor delivers an areal capacitance of 0.37 F cm(-2) and a volumetric energy density of 0.082 mW h cm(-3), which can well-maintain the specific capacitance even at -20 degrees C with over 85.2% retention after five cut/healing cycles.
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