期刊
CATALYSTS
卷 11, 期 5, 页码 -出版社
MDPI
DOI: 10.3390/catal11050558
关键词
transfer hydrogenation; furfurals; furfurylamine; reductive amination; Ru-MACHO
资金
- VILLUM FONDEN [19049]
A novel method utilizing homogeneous organometal-catalyzed transfer hydrogenation was developed for the selective reductive amination of furfurals to furfurylamines. The efficient and base-free process, employing Ru-MACHO-BH as catalyst and iPrOH as H donor, demonstrated good tolerance for a range of substituents, yielding moderate to excellent results.
We report the first example of employing homogeneous organometal-catalyzed transfer hydrogenation for the selective reductive amination of furfurals to furfurylamines. An efficient, chemoselective, and base-free method is described using Ru-MACHO-BH as catalyst and iPrOH as H donor. The method tolerates a range of substituents affording moderate to excellent yields.
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