The recent progress of pitch-based carbon anodes in sodium-ion batteries

Sodium-ion batteries (SIBs) have attracted significant attentions as promising alternatives to lithium-ion batteries for large-scale energy storage applications. Here carbon materials are considered as the most competitive anodes for SIBs based on their low-cost, abundant availability and excellent structural stability. Pitch, with high carbon content and low cost, is an ideal raw precursor to prepare carbon materials for large-scale applications. Nevertheless, the microstructures of pitch-based carbon are highly ordered with smaller interlayer distances, which are unfavorable for Na ion storage. Many efforts have been made to improve the sodium storage performance of pitch-based carbon materials. This review summarizes the recent progress about the application of pitch-based carbons for SIBs anodes in the context of carbon's morphology and structure regulation strategies, including morphology adjustment, heteroatoms doping, fabricating heterostructures, and the increase of the degree of disorder. Besides, the advantages, present challenges, and possible solutions to current issues in pitch-based carbon anode are discussed, with the highlight of future research directions. This review will provide a deep insight into the development of low-cost and high-performance pitch-based carbon anode for SIBs. (C) 2020 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by ELSEVIER B.V. and Science Press. All rights reserved.

Automated summary

Sodium-ion batteries (SIBs) are gaining attention as alternatives to lithium-ion batteries for large-scale energy storage, with carbon materials considered competitive anodes due to their low cost and structural stability. Pitch, a raw material with high carbon content and low cost, is ideal for producing carbon materials. However, the ordered microstructures of pitch-based carbon negatively impact sodium ion storage. Efforts to improve sodium storage performance include morphology adjustments, heteroatoms doping, fabricating heterostructures, and increasing disorder. This review provides insight into developing low-cost, high-performance pitch-based carbon anodes for SIBs.