期刊
JOURNAL OF ENERGY CHEMISTRY
卷 64, 期 -, 页码 323-334出版社
ELSEVIER
DOI: 10.1016/j.jechem.2021.04.061
关键词
Silica nanosheets; Vermiculite; High-temperature proton exchange membrane; Proton conductivity
资金
- EPSRC [EP/009050/1]
- Henry Royce Institute for Advanced Materials - EPSRC [EP/S019367/1, EP/P025021/1, EP/R00661X/1, EP/P025498/1]
By incorporating silica nanosheets (SN) into PES-PVP polymer matrix, the high-temperature proton exchange membrane showed enhanced proton conductivity and power density, demonstrating the potential of using SN in HT-PEMs production.
Silica nanosheets (SN) derived from natural vermiculite (Verm) were successfully incorporated into polyethersulfone-polyvinylpyrrolidone (PES-PVP) polymer to fabricate high-temperature proton exchange membranes (HT-PEMs). The content of SN filler was varied (0.1-0.75 wt%) to study its influence on proton conductivity, power density and durability. Benefiting from the hydroxyl groups of SN that enable the formation of additional proton-transferring pathways, the inorganic-organic membrane displayed enhanced proton conductivity of 48.2 mS/cm and power density of 495 mW/cm(2) at 150 degrees C without humidification when the content of SN is 0.25 wt%. Furthermore, exfoliated SN (E-SN) and sulfonated SN (S-SN), which were fabricated by a liquid-phase exfoliation method and silane condensation, respectively, were embedded in PES-PVP polymer matrix by a simple blending method. Due to the significant contribution from sulfonic groups in S-SN, the membrane with 0.25 wt% S-SN reached the highest proton conductivity of 51.5 mS/cm and peak power density of 546 mW/cm(2) at 150 degrees C, 48% higher than the pristine PES-PVP membranes. Compared to unaltered PES-PVP membrane, SN added hybrid composite membrane demonstrated excellent durability for the fuel cell at 150 degrees C. Using a facile method to prepare 2D SN from natural clay minerals, the strategy of exfoliation and functionalization of SN can be potentially used in the production of HT-PEMs. (C) 2021 The Authors. Published by ELSEVIER B.V. and Science Press on behalf of Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences.
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