期刊
ASIAN JOURNAL OF ORGANIC CHEMISTRY
卷 10, 期 8, 页码 1897-1937出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ajoc.202100182
关键词
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资金
- SERB-DST, New Delhi, India [CRG/2020/001769]
- CSIR, New Delhi, India [01(2935)/18/EMR-II]
- BRNS, Mumbai, India [58/14/17/2020-BRNS/37215]
- IIT Indore
- MHRD, Government of India
- UGC, New Delhi
Earth-abundant transition metal based catalytic materials are essential for clean chemical manufacturing, replacing expensive noble metal based catalytic systems. Copper based catalytic systems are effective in promoting functionalization of organic substrates and organic transformations. Nitriles, as a significant class of nitrogen-containing compounds, have various applications in pharmaceutical and fine chemical industries.
Earth-abundant transition metal based catalytic materials can become pivotal for clean chemical manufacturing due to their facile handling and air moisture stability replacing conventional expensive noble metal based catalytic systems. Amongst the non-noble metals, copper based catalytic systems due to the variable oxidation states have been effectively used as the tunable and multifunctional catalytic materials for the promotion of selective organic transformations. These copper based catalytic systems effectively promote multifarious organic transformations promoting functionalization of the easily available organic substrates. Nitriles are a significant class of nitrogen-containing compounds finding applications in pharmaceutical and fine chemical industries. Several organic and inorganic cyanide sources have been effectively usedto cyanate organic compounds by using multi-ferrous copper catalysts. Furthermore, nitrile compounds are key components used for the synthesis of drug molecules and fabrication of functionalized materials.
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