期刊
ADVANCED OPTICAL MATERIALS
卷 9, 期 16, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adom.202100421
关键词
anti‐ counterfeiting; carbonized polymer dots; phosphorescence; thermally stimulated; topological transition
资金
- Natural Science Foundation of Shandong Province [ZR2020QE052]
- National Natural Science Foundation of China (NSFC) [11774188]
- Mountain Tai Young Scholarship [23170504]
- Excellent Youth Foundation of Shandong's Natural Scientific Committee [JQ201802]
- Incubation Program of Universities' Preponderant Discipline of Shandong Province [03010304]
- Scientific Research Foundation for Doctors in Qilu University of Technology (Shandong Academy of Sciences) [81110306]
This study demonstrates the first multicolor room-temperature phosphorescence emission from carbon dots by utilizing a thermally driven amorphous-crystalline phase transition to achieve tunable emission colors. The development of carbonized polymer dots with potential applications as printable and writable security inks paves the way for the advancement of multicolor room-temperature phosphorescence materials.
Multicolor carbon dot (CD)-based nanomaterials offer a variety of opportunities for potential applications in bioimaging, optoelectronic devices, and information security. However, it still remains a challenge to modulate the conjugated pi-structure of CDs to achieve multicolor room-temperature phosphorescence (RTP). Herein, the authors present a strategy based on thermally driven amorphous-crystalline phase transition to achieve multicolor carbonized polymer dots (CPDs) with the emission color tunable from green to orange-red. This is the first report on multicolor RTP emission from CDs by means of thermal stimulus. Further investigations reveal that the formation of self-protective covalently crosslinked frameworks and codoping of multiple heteroatoms play a crucial role in the production of RTP. RTP color tunability can be attributed to different crystalline contents of the conjugated pi-domain within CPDs. Potential application of the developed CPDs as printable and writable security inks for advanced multilevel anti-counterfeiting and encryption is demonstrated. This work paves a path for the development of multicolor RTP materials and suggests great potential of CDs in exploiting novel optical materials toward intriguing applications.
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