期刊
POLYMERS
卷 13, 期 7, 页码 -出版社
MDPI
DOI: 10.3390/polym13071050
关键词
polymer gel electrolyte; chloroaluminate ionogel; imidazolium ionic liquid; aluminium secondary battery
资金
- Project European Union H2020-FETOPEN-1-2016-2017 [766581]
Polymer gel electrolytes based on imidazolium ionic liquids and a deep eutectic mixture have been prepared, showing rheology and electrochemical activity dependent on the molar ratio of charged groups and copolymer content. Spectroscopic analysis revealed interactions between the polymer and uralumina, and despite the need for improvement, these gels show promise as electrolyte alternatives for secondary aluminum batteries.
Polymer gel electrolytes (PGEs) have been prepared with copolymers based on imidazolium ionic liquids and the deep eutectic mixture of AlCl3:urea (uralumina) as liquid electrolyte. The copolymers were synthesized by photopolymerization of vinylpirrolidone or methylmethacrylate with imidazolium bis (trifluoromethane sulfonyl) imide (TFSI) ionic liquid monomer and mixed in an increasing range of wt.% with uralumina. The rheology and electrochemical activity of PGEs were highly dependent on the molar ratio of charged groups and copolymer content. Structure of the PGEs was studied by FTIR and Raman spectroscopy and a correlation between interactions polymer/uralumina and changes in speciation of uralumina was established. Despite the low molecular weight of the copolymers, the resulting polymer electrolytes develop elastomeric character associated with the binding ionic species. Although there is room to improve the electrochemical activity, in this study these new gels provide sufficient electroactivity to make them feasible alternatives as electrolytes in secondary aluminum batteries.
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