Effect of Sintering Process on Ionic Conductivity of Li7-xLa3Zr2-xNbxO12 (x=0, 0.2, 0.4, 0.6) Solid Electrolytes

Garnet-type Li7La3Zr2O12 (LLZO) is considered as a promising solid electrolyte. Nb-doped LLZO ceramics exhibit significantly improved ion conductivity. However, how to prepare the Nb-doped LLZO ceramics in a simple and economical way, meanwhile to investigate the relationship between process conditions and properties in Li7-xLa3Zr2-xNbxO12 ceramics, is particularly important. In this study, Li7-xLa3Zr2-xNbxO12 (LLZN(x)O, x = 0, 0.2, 0.4, 0.6) ceramics were prepared by conventional solid-state reaction. The effect of sintering process on the structure, microstructure, and ionic conductivity of LLZN(x)O (x = 0, 0.2, 0.4, 0.6) ceramics was investigated. Due to the more contractive Nb-O bonds in LLZN(x)O ceramics, the cubic structures are much easier to form and stabilize, which could induce the decreased preparation time. High-performance garnet LLZN(x)O ceramics can be obtained by optimizing the sintering process with lower calcining temperature and shorter holding time. The garnet samples with x = 0.4 calcined at 850 degrees C for 10 h and sintered at 1250 degrees C for 4 h exhibit the highest ionic conductivity of 3.86 x 10(-4) S center dot cm(-1) at room temperature and an activation energy of 0.32 eV, which can be correlated to the highest relative density of 96.1%, and good crystallinity of the grains.

Automated summary

In this study, Nb-doped Li7La3Zr2O12 ceramics were prepared by conventional solid-state reaction, and the effects of sintering process on their structure, microstructure, and ionic conductivity were investigated. By optimizing the sintering process, high-performance garnet LLZN(x)O ceramics were obtained with improved ionic conductivity.