4.6 Article

Ni-Al layered double hydroxides electrodeposition from a chloride solution

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Summary: The electrodeposition of alpha-Ni(OH)(2) from NiCl2 solution through membrane electrolysis method has been studied, showing that ethanol effectively poisons a side reaction of Ni2+ to Ni, resulting in the preferred formation of the product. The linear relationship between product mass and electrodeposition time in 0.1 M NiCl2 solutions suggests that the output of Ni is overlooked. In different concentration electrolytes, beta-Ni(OH)(2) and alpha-Ni(OH)(2) were synthesized, with beta-Ni(OH)(2) formation being prevented by circulating the cathodic electrolyte.

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