期刊
ACS CATALYSIS
卷 11, 期 11, 页码 6578-6589出版社
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.1c01201
关键词
catalysis; S(VI) fluorides; sulfur-fluoride exchange (SuFEx); sulfonyl fluorides; fluorosulfates; sulfamoyl fluorides; sulfonimidoyl fluorides
资金
- National Institute of General Medical Sciences of the National Institutes of Health [R15GM134457]
- Natural Sciences and Engineering Resource Council of Canada [2020-RGPIN-04653]
- University of British Columbia (UBC)
In the past decade, there has been remarkable growth in catalytic transformations in organic sulfur(VI) fluoride chemistry. This article focuses on foundational examples utilizing catalytic strategies to synthesize and react S(VI) fluorides, with an emphasis on key mechanistic studies aimed at providing insight for future catalytic systems.
The past decade has witnessed remarkable growth of catalytic transformations in organic sulfur(VI) fluoride chemistry. This Perspective concentrates exclusively on foundational examples that utilize catalytic strategies to synthesize and react S(VI) fluorides. Key mechanistic studies that aim to provide insight toward future catalytic systems are emphasized.
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